-
ity:proportion of stereoregular polymer in
total polymer.
uration:The fixed
spatial arrangement of atoms in organic molecules
-growth
polymerization:step/wise
reaction
between
the
funcional
groups
of
reactants.
-growth
polymerization:initiator species R* with a
reactive center-free radical. Cation
l
polymerization:The polymerization
which has no termination and transfer
radical polymerization: The polymerization which
uses free radical for chain-initiation
tion:The first process of
polymerization which produce free radical
polymerization
on
polymeriza
tion
:
The
polymerization
which
uses
emulsifier
for
making
the
monomer become emulsion in water
sion polymerization:The
polymerization which adds initiators to the
suspension in
water.
mation:three dimensional geometric
arrangement of the polymer, which changes
easily when the bonds are rotated.
17:excluded volume: one part of a long
chain molecule can not occupy space that is
already
occupied by another part of the
same molecule
llinity:
is
usually
specified
as
a
percentage
of
the
volume
of
the
material
that
is
crystalline.
crystal: A
solid in which the crystal lattice of the entire
sample is continuous and
unbroken to
the edges of sample,with no grain boundaries.
lite:Typia for spherulites arethe
maltese crosses which indicate the orientation of
polarizer and analyzer and the ring
patterns.
s of crystallization:
-
order
phase
transition:
A
first-order
transition
is
defined
as
on
for
which
a
discontinuity occurs in the first
derivative of the Gibbs free energy
-order phase transition:
Glass transition Temperature: the
temperature that marks the
chain
’
s transition from the
frozen state to the moving state is
called the Tg.
volume:the
unoccupied
space
in
a
sample
arising
from
the
inefficient
packing
of
disordered chains in the
amorphous regions.
stiffness:the difficulty with which the backbone
chain bonds can rotate.
31. Rheology:
The material deformation and flow properties under
the action of external
force , mainly
refers to the connections between viscosity and
stress deformation strain rate
in the
processing,
32. Newtonian fluid: Newton
fluid is a low viscous fluid, the rate between
shear stress and
deformation is
proportional .
33. Shear-thinning: Is a
phenomenon, in the processing of pseudo plastic
fluid, the apparent
viscosity decreases
with the increase of shear stress .
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